Epidemiology


Etiology


  • Dapsone
  • Local/topical anesthetics (eg, benzocaine, teething medications)
  • Nitrates/nitrites (eg, drinking ground water)

Pathophysiology


  • Methemoglobin is created when reduced ferrous iron (Fe2+) bound to oxyhemoglobin is oxidized to ferric iron (Fe3+).
  • Ferric iron in methemoglobin cannot bind oxygen→ ↓ total blood oxygen content and ↓ blood oxygen saturation → tissue hypoxia

Tip

The ferric iron in methemoglobin has a high affinity for cyanide, thus, amyl nitrite-induced methemoglobin is used as a competitive inhibitor in the treatment of cyanide poisoning.

Clinical features


  • Cyanosis (brownish-blue or gray skin and membranes)Pasted image 20240505095252.png

Diagnostics


Treatment


  • Methylene blue is the first-line treatment for acquired methemoglobinemia.
    • Acts as a cofactor to reduce methemoglobin to hemoglobin

Tip

100% supplemental oxygen is not useful in methemoglobinemia, in contrast to monoxide poisoning and cyanide poisoning.